A fast redox-induced switching mechanism in a conformationally controllable molecular thread in solution.

نویسندگان

  • Costantino Zazza
  • Giordano Mancini
  • Andrea Amadei
  • Nico Sanna
  • Massimiliano Aschi
چکیده

Irreversible redox-induced relaxation processes occurring in a synthetic thread for rotaxane-based molecular devices are investigated; the results show that such a system in solution allows chemists to efficiently realize a nanosecond timescale/electrochemically-driven "conformational shaping" through simple control of non-covalent interactions.

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عنوان ژورنال:
  • Physical chemistry chemical physics : PCCP

دوره 12 18  شماره 

صفحات  -

تاریخ انتشار 2010